Epoxidation Studies of Decalin-1,4-dienones and related Alcohols

Guillermo Labadie; Raquel Cravero; Manuel Gonzalez-Sierra

doi:10.3390/ecsoc-4-01813

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Epoxidation Studies of Decalin-1,4-dienones and related Alcohols

Guillermo R. Labadie

Raquel M. Cravero

Manuel Gonzalez-Sierra

¹ IQUIOS-(Instituto de Química Orgánica de Síntesis), Departamento de Química Orgánica, Facultad de Ciencias Bioquímicas y Farmacéuticas, UNIVERSIDAD NACIONAL DE ROSARIO. Suipacha 531- SL2002LRK-Rosario-Santa Fe- ARGENTINA

Published: 11 September 2000 by MDPI in The 4th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-4-01813

Abstract: The regio- and diastereoselectivities of epoxidations of decalin-1,4 -dienones and dienols obtained from the Birch reduction alkylation of different a-tetralones is described. They appear to depend on the steric approach control of the peracid and show an important contribution of the directing effect of homoallylic alcohols

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Guillermo Labadie

Raquel Cravero

Manuel Gonzalez-Sierra