The 8th International Electronic Conference on Synthetic Organic Chemistry
Part of the Electronic Conference on Synthetic Organic Chemistry series
1–30 Nov 2004
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- Event Details
Welcome from the Chairs
Call for Papers
Instructions for Authors
Authors are encouraged to preare a couple of slides in PowerPoint or similar software, to be displayed online along with the Communication. Slides can be prepared in exactly the same way as for any traditional conference where research results can be presented. Slides should be converted to PDF format before submission.
Submissions should be done by the authors online by registering with www.sciforum.net, and using the "New Submission" function once logged into system.
MDPI AG, the publisher of the Sciforum.net platform, is an open access publisher. We believe that authors should retain the copyright to their scholarly works. Hence, by submitting a Communication paper to this conference, you retain the copyright of your paper, but you grant MDPI AG the non-exclusive right to publish this paper online on the Sciforum.net platform. This means you can easily submit your paper to any scientific journal at a later stage and transfer the copyright to its publisher (if required by that publisher).
List of accepted submissions (63)
Id | Title | Authors | Poster PDF | ||||||||||||||||||||||||||||||||||||||
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sciforum-001017 | Deprotection of N-Pivaloylindoles, Carbazoles and Beta-Carbolines with a Lithium Base |
J. Sánchez ,
Carmen Avendaño ,
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N/A |
Show Abstract |
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Treatment of a variety of pivaloylindoles, carbazoles and with LDA at 40-45 °C led to their fast and efficient deprotection. | |||||||||||||||||||||||||||||||||||||||||
sciforum-001018 |
DTBB-Catalysed Lithiation of Cis- and Trans-2,3-diphenyloxirane Gives the Same Organolithium Intermediate
Larry Falvello ,
Cecilia Gómez ,
Beatriz Maciá ,
Tatiana Soler ,
Submitted: 31 Oct 2004 Abstract: Show Abstract |
Larry Falvello ,
Cecilia Gómez ,
Beatriz Maciá ,
Tatiana Soler ,
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N/A |
Show Abstract |
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The reaction of cis- or trans-2,3-diphenyloxirane with lithium powder and a catalytic amount of 4,4’-di-tert-butylbiphenyl (DTBB, 5% molar) in the presence of 3-pentanone as electrophile in THF at temperatures ranging between –90 and –50ºC gives, after hydrolysis with water, the corresponding 1,3-diol 5 with the same stereochemistry (1S*,2R*) independently of the geometry of the starting oxiranes. A mechanistic explanation for this behaviour is given. | |||||||||||||||||||||||||||||||||||||||||
sciforum-001019 |
Enantiospecific Preparation of 10-(pyperidin-1-yl)Camphor: A Model Procedure for 10-Aminocamphors
Antonio García Martínez ,
Enrique Teso Vilar ,
Amelia García Fraile ,
Cristina Diaz Morillo ,
Santiago de la Moya Cerero
Submitted: 31 Oct 2004 Abstract: Show Abstract |
Antonio García Martínez ,
Enrique Teso Vilar ,
Amelia García Fraile ,
Cristina Diaz Morillo ,
Santiago de la Moya Cerero
|
N/A |
Show Abstract |
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Enantiopure (1R)-10-(pyperidin-1-yl)camphor has been straightforwardly obtained from natural camphor in five individual steps and with a high overall yield. The process involves a stereocontrolled double-Wagner-Meerwein-rearrangement strategy to generate 10-(triflyloxy)camphor as the key intermediate. This peculiarly-stable neopentylic-like triflate is able to react with pyperidine easily and without producing Grob-like fragmentation of the b-(triflyloxy)ketone-based norbornane system. The described procedure constitutes a model procedure for the sterecontrolled preparation of interesting 10-aminocamphors. | |||||||||||||||||||||||||||||||||||||||||
sciforum-001020 | Direct Synthesis of A-Hydroxy Acids Through Selective Oxidation of Diols Mediated by Homogeneous and Heterogeneous TEMPO |
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Pamela Gancitano ,
Rosaria Ciriminna ,
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N/A |
Show Abstract |
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sciforum-001021 | Synthesis and Spectral Characterization of a Fluorescent Marker |
Ana Piloto ,
Susana Costa ,
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N/A |
Show Abstract |
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List of Authors (58)
Proceedings & Editors
A. General Organic Synthesis
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C. Bioorganic Chemistry and Natural Products
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E. Symposium on Microwave Assisted Synthesis
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F. Supramolecular Chemistry
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