Amide formation from amino acids was achieved in an easy and convenient one-pot procedure in chloroform or tetrahydrofuran as solvent using di-tert-butyl dicarbonate both as a protecting and an activating agent in the absence of a catalyst or coupling reagent. A number of dipeptide has been thus synthesized in good yields. The structures of the dipeptides were confirmed by IR, NMR and mass spectral data.

A comparison among some catalysts, which have been already reported in the bibliography, for hydrogen production via the ethanol steam reforming reaction is done. The role of every studied active metallicspecie (Co, Ni, Cu and Zn species) and some supports (Al2O3, SiO2) in the ethanol steam reforming reaction pathway in the range of 300-500oC is found. The effect of the operation variables on conversion, yield, selectivity and catalyst stability is also studied. Taking into account that the ethanol steam reforming reaction could be a global chemical process of a small group of well known consecutive reactions, it is proposed that every different step in the ethanol steam reforming reaction can be consecutively and separately optimized using the most convenient catalyst for each one and not necessarily only one catalyst for the whole process.

Base-catalyzed dehydration of 2-cyanimino-4-hydroxy-4-methyl-5-tosylhexahydropyrimidines gives expected 2-cyanimino-5-tosyl-1,2,3,4-tetrahydropyrimidines. However, acid-catalyzed dehydration leads to mixture of the latter compounds and the products of tosyl group migration, namely 2-cyanimino-4-tosylmethyl-1,2,3,4-tetrahydropyrimidines. Plausible explanation of the obtained data is proposed.