Regioselectivity of Arylation of 2,3'-Biquinolyl Dianion

A. Aksenov; I. Aksenova; I. Borodaev; Yu. Smushkevich

doi:10.3390/ecsoc-1-02025

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The Synthesis of (2R,5R)-2-Amino-5-Hydroxyhexanoic Acid by Intermolecular Cycloaddition

Regioselectivity of Arylation of 2,3'-Biquinolyl Dianion

A. V. Aksenov

^{*

1},

I. V. Aksenova

¹,

I. V. Borodaev

¹,

Yu. I. Smushkevich

¹ Stavropol State University, Chair of Organic Chemistry, Stavropol 355009, Russia
² Russian Mendeleev University of Chemical Technology, Chair of Organic Chemistry, 9 Miusskaya sq., 125047 Moscow, Russia.

Published: 01 September 1997 by MDPI in The 1st International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

https://doi.org/10.3390/ecsoc-1-02025

Abstract: Dianion of 2,3'-biquinolyl with aryl- and hetaryl halides forms product of arylation to 4'-position, which on treatment with alkyl halides or water yield 1'-alkyl-1',4'dihydro-2,3'-biquinolyls or 4'-aryl-1',4'-dihydro-2,3'-biquinolyls respectively. The oxydation of the latter leads to 4'-aryl-2,3'-biquinolyls. The cation dependence of the arylation is shown.

Keywords: Regioselectivity, arylation, 2,3'-biquinolyl dianion

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A. Aksenov

I. Aksenova

I. Borodaev

Yu. Smushkevich