Ionic liquids (ILs) represents, nowadays, a real alternative for electrochemical applications such as organic solvents, electrolytes, dye-sensitized solar cells, lubricants and sensors among others, due to their amazing characteristics, namely a very low vapour pressure, low flammability, high thermal stability, wide potential window and high ionic conductivity. In this work, Nyquist plot and impedance spectroscopy at room temperature is proposed as an alternative method, using a RLC precision meter Agilent HP 4284 A, to obtain the ionic conductivity for ionic liquids in the frame of dielectric constant in the frequency range of 1 Hz to 1 MHz, by determination of the conductive regime through frequency dependence. For this propose, the IL 1-butyl-3-methylimidazolium tetrafluoroborate (C4C1Im BF4) was selected and results were compared with the previously obtained from the conductimeter CRISON GLP31 at a constant frequency of 500 Hz.
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Electrical conductivity and Nyquist plot of C4C1Im BF4 at room temperature by impedance spectroscopy
Published:
14 November 2020
by MDPI
in The 24th International Electronic Conference on Synthetic Organic Chemistry
session Ionic Liquids
Abstract:
Keywords: ionic liquid, dielectric spectroscopy, electrolytes, impedance