Event submissions
Published
This submission belongs to the session c. Microwave Assisted Synthesis of the event The 16th International Electronic Conference on Synthetic Organic Chemistry
Published date
26 Oct, 2012
Citation
Dariusz Bogdał, Szczepan Bednarz, Urszula Pisarek, Sylwia Dworakowska, Oxidation Reactions Using Tert-butyl Hydroperoxide/d-metal Chlorides Systems with Aid of Microwaves, in Proceedings of The 16th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2012, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-16-01128
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Oxidation Reactions Using Tert-butyl Hydroperoxide/d-metal Chlorides Systems with Aid of Microwaves
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Sylwia Dworakowska 1
Urszula Pisarek 1
Szczepan Bednarz 1
Dariusz Bogdał 1
1. Cracow University of Technology, 31-155 Cracow, Warszawska 24
Abstract
The aim of present work was to check the possibility of microwave irradiation application for benzylic oxidation of diphenylmethane. The investigations were carried out using tert-butyl hydroperoxide (TBHP) both under conventional and microwave conditions. The catalysts tested were chlorides of transition d-metals: FeCl3·6H2O, CoCl2·6H2O, NiCl2·6H2O, CrCl3·6H2O, CuCl2·2H2O, ZnCl2 and iodine. From all studied metal catalysts, FeCl3·6H2O, CoCl2·6H2O, NiCl2·6H2O, CrCl3·6H2O showed the best catalytic activity.
Keywords
microwave irradiation
benzylic oxidation
tert-butyl hydroperoxide
d-metal chlorides
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