EventsThe 16th International Electronic Conference on Synthetic Organic Chemistry
Published
This submission belongs to the session d. Polymer and Supramolecular Chemistry of the event The 16th International Electronic Conference on Synthetic Organic Chemistry
Published date
30 Oct, 2012
Citation
Dariusz Bogdał, Mateusz Galica, Synthesis of Polymeric Luminophores Based on the Carbazole Derivative and Terbium (III) Complexes, in Proceedings of The 16th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2012, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-16-01160
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Synthesis of Polymeric Luminophores Based on the Carbazole Derivative and Terbium (III) Complexes

Dariusz Bogdał 1
1. Cracow University of Technology
Abstract
This article focuses on the synthesis of a new polymeric phosphors containing Tb+3 ions as a potential material for next generation optoelectronic devices. Here we are presented the results of the synthesis and luminescence properties of copolymers containing: 2-(9-carbazolyl)ethyl methacrylate (CEM) and p-methacryloyloxybenzoic acid (pMBA) complexed with Tb(III). All copolymers have been characterized by HNMR, GPC, FTIR and UV-Vis. Solutions of the copolymers in THF or CHCl3 have been examined for their photoluminescence properties. Finally, the possibility of using these materials in optoelectronics were compared to those already synthesized.
Keywords
carbazole
salicylic acid
copolymer
ion
luminesce
terbium complex
Computational Studies of Optical Properties of (E)-2-(5-methacrylamido-2, 3-bis (methylthio) phenyl) Diazenesulfonate Dye for Solar Cell Using DFT and TD-DFT Methods