EventsThe 25th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-25-11631
This submission belongs to the session S2. Bioorganic, Medicinal and Natural Products Chemistry of the event The 25th International Electronic Conference on Synthetic Organic Chemistry
Published date
12 Nov, 2021
Academic Editor
author-avatarJulio A. Seijas
Citation
Gulnara Kadikova, Lilya Dzhemileva, Usein Dzhemilev, Synthesis of new functionally substituted bicyclo[4.2.1]nona-2,4,7-trienes by Co(I)-catalyzed [6π+2π] cycloaddition of 1-benzoylcycloheptatriene, in Proceedings of The 25th International Electronic Conference on Synthetic Organic Chemistry, 15 November–30 November 2021, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-25-11631
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Synthesis of new functionally substituted bicyclo[4.2.1]nona-2,4,7-trienes by Co(I)-catalyzed [6π+2π] cycloaddition of 1-benzoylcycloheptatriene

Gulnara Kadikova 1
image
Lilya Dzhemileva 1
Usein Dzhemilev 1
1. Institute of Petrochemistry and Catalysis of RAS (IPC RAS)
Abstract

Functionally substituted bicyclo[4.2.1]nona-2,4,7-trienes were synthesized for the first time on the basis of the reaction of [6π+2π] cycloaddition of hexyn-1 and 4-pentynenitrile to 1-benzoylcycloheptatriene under the action of the three-component catalytic system Co(acac)2(dppe)/Zn/ZnI2

Keywords
[6π+2π] cycloaddition
1-benzoylcycloheptatriene
alkynes
bicyclo[4.2.1]nona-2,4,7-trienes
cobalt(II) acetylacetonate
antitumor activity
Manuscript
sciforum_048087-11.4 done.pdf
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