EventsThe 25th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-25-11633
This submission belongs to the session S2. Bioorganic, Medicinal and Natural Products Chemistry of the event The 25th International Electronic Conference on Synthetic Organic Chemistry
Published date
12 Nov, 2021
Academic Editor
author-avatarJulio A. Seijas
Citation
Gulnara Kadikova, Lilya Dzhemileva, Usein Dzhemilev, Co(I)-catalyzed [4π+2π] cycloaddition of 1,2-dienes to 1,3,5-cyclooctatriene in the synthesis of previously undescribed tricyclo[4.2.2.02.5]decenes, in Proceedings of The 25th International Electronic Conference on Synthetic Organic Chemistry, 15 November–30 November 2021, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-25-11633
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Co(I)-catalyzed [4π+2π] cycloaddition of 1,2-dienes to 1,3,5-cyclooctatriene in the synthesis of previously undescribed tricyclo[4.2.2.02.5]decenes

Gulnara Kadikova 1
image
Lilya Dzhemileva 1
Usein Dzhemilev 1
1. Institute of Petrochemistry and Catalysis of RAS (IPC RAS)
Abstract

The catalytic [4π+2π]-cycloaddition of mono- and disubstituted 1,2-dienes to 1,3,5-cyclooctatriene under the action of Co(acac)2(dppe)/Zn/ZnI2 was performed for the first time to give substituted tricyclo[4.2.2.02.5]dec-7-enes.

Keywords
[4π+2π]-cycloaddition
1,3,5-cyclooctatriene
1,2-dienes
tricyclo[4.2.2.02.5]dec-7-enes
cobalt(II) acetylacetonate
antitumor activity
Manuscript
sciforum_048093_original_Kadikova_GN - done.pdf
Natural and synthetic dienoic and trienoic acids - an original method for the synthesis and antitumor activity.
Azide-Alkyne Cycloaddition Catalyzed by a Glucose/Benedict Reagent System