EventsThe 25th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-25-11634
This submission belongs to the session S1. General Organic Synthesis of the event The 25th International Electronic Conference on Synthetic Organic Chemistry
Published date
12 Nov, 2021
Academic Editor
author-avatarJulio A. Seijas
Citation
Erick Cuevas-Yañez, Jesús G. García Torres, Andrés Becerra-Buitrago, Luis Carlos García-Sánchez, Marco A. García-Eleno, M. V. Basavanag Unnamatla, Azide-Alkyne Cycloaddition Catalyzed by a Glucose/Benedict Reagent System, in Proceedings of The 25th International Electronic Conference on Synthetic Organic Chemistry, 15 November–30 November 2021, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-25-11634
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Azide-Alkyne Cycloaddition Catalyzed by a Glucose/Benedict Reagent System

Jesús G. García Torres 1
Andrés Becerra-Buitrago 2
Luis Carlos García-Sánchez 2
Marco A. García-Eleno 1
M. V. Basavanag Unnamatla 1
image
Erick Cuevas-Yañez 1,3
1. Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Carretera Toluca-Atlacomulco Km. 14.5, Toluca, Estado de México 50200, Mexico
2. Facultad de Ciencias y Educación, Universidad Distrital Francisco José de Caldas. Carrera 7 No. 40B - 53, Bogotá D.C, Colombia
3. Facultad de Química, Facultad de Química, Universidad Autónoma del Estado de México. Paseo Colón esq. Paseo Tollocan, 50120, Toluca, Mexico
Abstract

Benedict's Reagent is commonly used in identifying reducing sugars through a redox process where a Cu(I) species is generated. Despite the simplicity of this reaction, this has barely been investigated as a copper (I) source for catalytic processes. In this report, diverse organic azides and alkynes were reacted in presence of catalytic amounts of a Glucose-Benedict Reagent system, obtaining the corresponding 1,2,3-triazoles through a simple and environmentally friendly synthetic procedure.

Keywords
click chemistry
Benedict reagent
glucose
alkyne
azide
1,2,3-triazole
Manuscript
sciforum_048661_original_Benedict_oct2021-done.pdf
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