EventsThe 25th International Electronic Conference on Synthetic Organic Chemistry
Published
This submission belongs to the session S4. Polymer and Supramolecular Chemistry of the event The 25th International Electronic Conference on Synthetic Organic Chemistry
Published date
13 Nov, 2021
Academic Editor
author-avatarJulio A. Seijas
Citation
Vikas Patil, Lina Jadhav, Nikhil Borane, Rahul Patil, Ganapati D Yadav, Dipak B Patil, Satyendra Mishra, A Novel Synthetic Approach of Functionalised GO and CNT to Nanocomposite Containing Active Nanostructured Fillers for Classical Isocyanate Curing, in Proceedings of The 25th International Electronic Conference on Synthetic Organic Chemistry, 15 November–30 November 2021, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-25-11679
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A Novel Synthetic Approach of Functionalised GO and CNT to Nanocomposite Containing Active Nanostructured Fillers for Classical Isocyanate Curing

Lina Jadhav 2
Rahul Patil 2
Nikhil Borane 2
Satyendra Mishra 2
image
1. University Institute of Chemical Technology, KBC North Maharashtra University, Jalgaon
2. University Institute of Chemical Technology, Kavayitri Bahinabai Choudhari North Maharashtra University, Jalgaon, India 425001
3. Institute of Chemical Technology Mumbai
4. Universidad de Guanajuato, Campus Guanajuato, División de Ciencias Naturales y Exactas, Departamento de Química, Noria Alta S/N, 36050, Guanajuato, Guanajuato, México
Abstract

A novel synthetic method has been developed by utilizing the chemical reactivity of functionalized graphene and CNT with a covalent combination of chemically diverse GO/FCNT and toluene diisocyanate. Thereby yield a synergistic polymer nanocomposite. Comprehensive composite material has simultaneous covalent as well as π-π interactions confirms sp2-hybridized frameworks of graphene oxide and MWCNTs by Raman absorption spectra at 1345 and 1590 cm-1 of D and G band respectively. Toluene diisocyanate and GO/FCNT inspired polymeric formulation obtained by the classical curing reaction initiated by ultrasound sonication. This method allowed 50 wt. % doping of GO/FCNT without segregation ensures good adhesion to the law steel surface. Large surface area and morphological character of GO and FCNT by SEM and TEM ensure stable and dispersed integrated molecules. It has advantages over the high-temperature hazardous curing reaction overcomes the problem of graphene exfoliation and does not allow CNT slipping within the bundle to falls apart at higher concentration.

Keywords
Graphene
CNT
Isocyanate
Curing
Filler
Nanostructured
Manuscript
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