EventsThe 25th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-25-11718
This submission belongs to the session S1. General Organic Synthesis of the event The 25th International Electronic Conference on Synthetic Organic Chemistry
Published date
14 Nov, 2021
Academic Editor
author-avatarJulio A. Seijas
Citation
Hossein Ghafuri, Yegane Rostami, Nastaran Ghanbari, Behnaz Abbasi, Zeinab Tajik, Gum-supported melamine: a recyclable reagent for selective and metal-free oxidation of benzyl alcohols, in Proceedings of The 25th International Electronic Conference on Synthetic Organic Chemistry, 15 November–30 November 2021, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-25-11718
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Gum-supported melamine: a recyclable reagent for selective and metal-free oxidation of benzyl alcohols

Hossein Ghafuri 1
Yegane Rostami 2
Nastaran Ghanbari 2
Behnaz Abbasi 2
Zeinab Tajik 2
1. Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran16846-13114, Iran, Iran
2. Catalysts and Organic Synthesis Research Laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran16846-13114, Iran
Abstract

Novel melamine functionalized gum (gum@Melamine) is synthesized, and its catalytic performance is investigated in the oxidation of benzyl alcohols. The gum@Melamine was prepared through grafting of 3-chloropropyltrimethoxysilane on gum followed by treatment with melamine. The synthesized gum@Melamine was used to achieve an effective and selective method for the oxidation of different alcohols. All substituted benzyl alcohols were oxidized in good yields under mild conditions at room temperature. This gum@Melamine has great stability and could be recycled five times without noteworthy loss of activity.

Keywords
melamine
gum
oxidation of benzyl alcohols.
Manuscript
sciforum_051250-done.pdf
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