Events The 25th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

10.3390/ecsoc-25-11761 (registering DOI)

This submission belongs to the session S1. General Organic Synthesis of the event The 25th International Electronic Conference on Synthetic Organic Chemistry

Published date

14 Nov, 2021

Academic Editor

Julio A. Seijas

Citation

Marcos Rúa Sueiro, Juan M. Ortigueira, José M. Vila, Cyclometallated thiosemicarbazones containing fluorine atoms: a solubility improvement, in Proceedings of The 25th International Electronic Conference on Synthetic Organic Chemistry, 15 November–30 November 2021, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-25-11761

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Cyclometallated thiosemicarbazones containing fluorine atoms: a solubility improvement

Marcos Rúa Sueiro ¹

Juan M. Ortigueira ²

José M. Vila ²

1. Department of Inorganic Chemistry, Faculty of Chemistry, University of Santiago de Compostela, Avda. das Ciencias s/n, 15782, Spain

2. Department of Inorganic Chemistry, Faculty of Chemistry, University of Santiago de Compostela, Santiago de Compostela

Abstract

A novel set of thiosemicarbazone palladacycles is discussed. The addition of a fluorine atom to the thiosemicarbazone ligand increases not only the solubility of the ligand itself, but also that of the ensuing cyclometallated complexes.

Ligands are synthesized in acidic ethanolic solution, and then reacted with potassium tetrachloropalladate(II), to give the corresponding cyclopalladated compounds bearing a tetranuclear structure.

Characterization will be carried by IR, ¹H NMR and ¹⁹F NMR spectroscopies.

Keywords

thiosemicarbazone

palladium

cyclometallation

fluor

solubility

Manuscript

sciforum_051700.pdf

A novel heterocyclic thiosemicarbazone: synthesis, characterization and preliminary sensing studies for ions

Synthesis and characterization of amine functionalized thiosemicarbazone cyclopalladated compounds.