Events The 25th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session S1. General Organic Synthesis of the event The 25th International Electronic Conference on Synthetic Organic Chemistry

Published date

14 Nov, 2021

Academic Editor

Julio A. Seijas

Citation

Francisco Reigosa Chamorro, José Manuel Vila, María Teresa Pereira, Synthesis and characterization of amine functionalized thiosemicarbazone cyclopalladated compounds., in Proceedings of The 25th International Electronic Conference on Synthetic Organic Chemistry, 15 November–30 November 2021, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-25-11762

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Synthesis and characterization of amine functionalized thiosemicarbazone cyclopalladated compounds.

Francisco Reigosa Chamorro ¹

María Teresa Pereira ¹

José Manuel Vila ¹

1. University of Santiago de Compostela, Department of Inorganic Chemistry

Abstract

Differences in the functional groups of the ligands can change the properties of the cyclometallated compounds and modify their suitability for various applications, such as catalysis and biomedicine.

Herein we report the synthesis and characterization of a new series of cyclometallated palladium compounds bearing an amine-functionalized thiosemicarbazone. The synthesis of the ligands was achieved by condensation of the thiosemicarbazide and aminoacetophenone. Reaction of the ligands with an appropriate metalating agent gave rise to the tetranuclear cyclometallated compounds.

The compounds were characterized by EA, 1H-NMR and IR spectroscopy.

Keywords

Thiosemicarbazone

palladium

cyclometallation

Manuscript

sciforum_051701.pdf

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