This submission belongs to the session a. General Organic Synthesis of the event The 12th International Electronic Conference on Synthetic Organic Chemistry
Published date
28 Nov, 2008
Citation
Didier Villemina, Mohammed Benabdallah, Nadjib Rahmounb, Noureddine Choukchou-Braham, Bachir Mostefa-Karab, Synthesis of New 2-(3-Hydroxy-4-oxo-4Hnaphthalenylidene) acetonitriles in Aqueous Solvent, in Proceedings of The 12th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2008, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-12-01202
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Synthesis of New 2-(3-Hydroxy-4-oxo-4Hnaphthalenylidene) acetonitriles in Aqueous Solvent
Didier Villemina 1
Mohammed Benabdallah 1,2
Nadjib Rahmounb 2
Noureddine Choukchou-Braham 2
Bachir Mostefa-Karab 2
1. ENSICAEN, LCMT-UMR 6507 CNRS, Université de Caen, 14050 Caen, France
2. Laboratoire de Catalyse et Synthèse en Chimie Organique, Faculté des Sciences, Université Abou-Bakr Belkaid, BP 119, 13000 Tlemcen, Algérie
Abstract
We have prepared a serie of new naphthoquinomethanes: [2-(3-hydroxy-4-oxo-4H-naphthalen-1-ylidene) acetonitriles] by the cascade Michael-elimination reaction of sodium 1, 2-naphthoquinone-4-sulfonate with substituted acetonitriles in basic ethanol-water.
Keywords
lawson
antibacterial
Michael addition
3-hydroxy-1,2-naphthoquinomethane
green chemistry
Sonogashira versus Stephens-Castro Mediated Synthesis of o-Phenylethynylbenzoic Acids, Convenient Precursors of 3-Phenylisocoumarins
Benzylic Newman-Kwart rearrangement triggered by Phosphanes