This submission belongs to the session a. General Organic Synthesis of the event The 12th International Electronic Conference on Synthetic Organic Chemistry
Published date
28 Nov, 2008
Citation
M. Marín-Luna, M. Alajarín, M.-M. Ortín, P. Sánchez-Andrada, A. Vidal, Benzylic Newman-Kwart rearrangement triggered by Phosphanes, in Proceedings of The 12th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2008, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-12-01203
Share
Email
Facebook
Twitter
LinkedIn
Benzylic Newman-Kwart rearrangement triggered by Phosphanes
M. Marín-Luna
M. Alajarín
M.-M. Ortín
P. Sánchez-Andrada
A. Vidal
Abstract
A Staudinger imination reaction of tertiary phosphanes with O-(azidobenzyl)thioncarbamates, bearing the azido function at ortho or para position, promotes a rare benzylic Newman-Kwart rearrangement.
Keywords
n/a
Synthesis of New 2-(3-Hydroxy-4-oxo-4Hnaphthalenylidene) acetonitriles in Aqueous Solvent
Convenient synthesis of some methyl-N-[2-(6-oxo-3-p-tolyl-5,6-dihydro-4H-pyridazin-1-yl)-acetamide]alkanoates