EventsThe 12th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-12-01225
This submission belongs to the session a. General Organic Synthesis of the event The 12th International Electronic Conference on Synthetic Organic Chemistry
Published date
11 Nov, 2008
Citation
M. A. Vázquez-Fernández, M. I. Fernández, B. Fernández, A. M. González-Noya, M. Maneiro, M. J. Rodríguez-Doutón, Synthesis of Multidentate Schiff Base Ligands. Crystal Structure of (N-N’-BIS(3-Ethoxysalicylidene)-1,3-Diamino-2,2-Dimethylpropane, in Proceedings of The 12th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2008, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-12-01225
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Synthesis of Multidentate Schiff Base Ligands. Crystal Structure of (N-N’-BIS(3-Ethoxysalicylidene)-1,3-Diamino-2,2-Dimethylpropane

M. A. Vázquez-Fernández 1
M. I. Fernández 1
B. Fernández 1
A. M. González-Noya 1
M. Maneiro 1
M. J. Rodríguez-Doutón 1
1. Dpto. de Química Inorgánica. Facultad de Ciencias. Univ. de Santiago de Compostela. 27002 Lugo(Spain)
Abstract
The hexadentate Schiff base ligands were prepared by condensation of 3-ethoxy-2-hydroxybenzaldehyde and different diamines (1,3-diaminopropane, 1,3-diamino-2,2-dimethylpropane, 1,4-diaminobutane) to yield H2Ln (H2L1, H2L2 and H2L3, respectively). The ligands have been characterised by elemental analysis, IR, 1H and 13C NMR spectroscopies and mass spectrometry (ES). The crystal structure of the H2L2 ligand was solved by X-ray crystallography, revealing its ability to bind metal centres.
Keywords
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