This submission belongs to the session a. General Organic Synthesis of the event The 12th International Electronic Conference on Synthetic Organic Chemistry
Published date
01 Nov, 2008
Citation
Mohammad G. Dekamin, Javad Mokhtari, M. Reza Naimi-Jamal, Tetrabutylammonium phtalimide-N-oxyl (TBAPINO) as an efficient, safe and recoverable catalyst for rapid trimethylsilyl protection of hydroxyl groups, in Proceedings of The 12th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2008, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-12-01235
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Tetrabutylammonium phtalimide-N-oxyl (TBAPINO) as an efficient, safe and recoverable catalyst for rapid trimethylsilyl protection of hydroxyl groups
Mohammad G. Dekamin 1
Javad Mokhtari 1
M. Reza Naimi-Jamal 1
1. College of Chemistry, Iran University of Science and Technology, Tehran, 16846-13114, Iran
Abstract
Tetrabutylammonium phtalimide-N-oxyl (TBAPINO) can be used as an efficient organocatalyst for the conversion of alcohols to their corresponding trimethylsilyl ethers with hexamethyldisilazane (HMDS). All reactions were performed under mild and completely homoogeneous reaction conditions in high to quantitative yields.
Keywords
n/a
Synthesis of 1,2,4,5-benzenetetracarboxylic dianhydride – 4,4’-diaminodiphenyl ether 1 : 2 and 2 : 1 condensation products
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