Events The 12th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session d. Symposium on Selenium and Tellurium Chemistry of the event The 12th International Electronic Conference on Synthetic Organic Chemistry

Published date

30 Nov, 2008

Citation

Claudio Santi, Stefano Santoro, Fabio Pascolini, Cristina Tomassini, Marcello Tiecco, Asymmetric methoxyselenenylation of α,b-unsatured carbonyl derivatives, in Proceedings of The 12th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2008, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-12-01249

Facebook

Twitter

Asymmetric methoxyselenenylation of α,b-unsatured carbonyl derivatives

Claudio Santi ¹

Stefano Santoro ¹

Fabio Pascolini ¹

Cristina Tomassini ¹

Marcello Tiecco ¹

1. Dipartimento di Chimica e Tecnologia del Farmaco – Università di Perugia – Italy

Abstract

In this communication we propose a convenient methodology to effect asymmetric methoxyselenenylation of a,b-unsatured carbonyl derivatives using as electrophilic reagents an optically pure sulfur containing selenenyl chloride. Mechanistic aspects of the reaction were investigated and simple manipulation to prepare optically pure derivatives are reported.

Keywords

n/a

Ring-substituted 4-Hydroxy-1H-quinolin-2-ones: Preparation and Their Photosynthesis-inhibiting Activity

Comparison of the Reactivity Between Nitrothiophenes and Nitroselenophenes in Polar Cycloaddition Reactions