EventsThe 12th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-12-01250
This submission belongs to the session d. Symposium on Selenium and Tellurium Chemistry of the event The 12th International Electronic Conference on Synthetic Organic Chemistry
Published date
29 Nov, 2008
Citation
Claudia Della Rosa, Maria Kneeteman, Pedro M. E. Mancini, Comparison of the Reactivity Between Nitrothiophenes and Nitroselenophenes in Polar Cycloaddition Reactions, in Proceedings of The 12th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2008, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-12-01250
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Comparison of the Reactivity Between Nitrothiophenes and Nitroselenophenes in Polar Cycloaddition Reactions

Claudia Della Rosa 1
Maria Kneeteman 1
Pedro M. E. Mancini 1
1. Área Química Orgánica- Departamento de Química - Facultad de Ingeniería Química, Universidad Nacional del Litoral. Santiago del Estero 2829- 3000 Santa Fe, Argentina
Abstract
Dienophilic behaviour of nitrothiophenes and nitroselenophenes towards Diels-Alder reactions with dienes of medium nucleophilicity is studied under thermal conditions. While nitrated thiophenes reacted via Hetero Diels-Alder, nitrated selenophenes followed the normal process.
Keywords
nitrothiophenes
nitroselenophenes
Diels-Alder
Asymmetric methoxyselenenylation of α,b-unsatured carbonyl derivatives
Microwave-assisted oxidation of a secondary alcohol using a Gold catalyst immobilized onto gel-supported Ionic Liquid like phases (g-SILLPs)