Events The 12th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session e. Symposium on Microwave Assisted Synthesis of the event The 12th International Electronic Conference on Synthetic Organic Chemistry

Published date

17 Nov, 2008

Citation

Alexandra Pérez-Anes, Patricia García-García, Manuel A. Fernández-Rodríguez, Enrique Aguilar, Microwave-Accelerated Multi-Component Cascade Reactions Involving Fischer Alkoxy Alkynyl Carbene Complexes, in Proceedings of The 12th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2008, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-12-01264

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Microwave-Accelerated Multi-Component Cascade Reactions Involving Fischer Alkoxy Alkynyl Carbene Complexes

Alexandra Pérez-Anes ¹

Patricia García-García ¹

Manuel A. Fernández-Rodríguez ¹

Enrique Aguilar ¹

1. Instituto Universitario de Química Organometálica “Enrique Moles”, Unidad Asociada al CSIC, Universidad de Oviedo, Julián Clavería 8, 33006, Oviedo (Spain)

Abstract

The sequential [2+2]/[2+1] and [2+2+1]/[2+1] multicomponent reactions that occur thermally when treating alkoxy alkynyl Fischer carbene complexes with 2,3-dihydrofuran or norbornene may be accelerated by MW irradiation. They lead to the same adducts in similar yields and diastereoselectivities and, therefore, MW irradiation does not cause a different chemical behaviour but just an accelerating effect.

Keywords

n/a

Microwave-assisted solvent-free synthesis of N,N-bis(salicylidene)-2,2-dimethylpropane-1,3-diamine

Temperature and Time Optimization of Diels-Alder Reactions in the CEM Microwave