Events The 12th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session f. Supramolecular Chemistry of the event The 12th International Electronic Conference on Synthetic Organic Chemistry

Published date

27 Nov, 2008

Citation

Alvaro Antelo, Mercedes Alvarez Alcalde, Aida Jover, Francisco Meijide, Luciano Galantini, José Vázquez Tato, Supramolecular polymer formed by ditopic cyclodextrin and ditopic adamantane derivatives, in Proceedings of The 12th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2008, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-12-01270

Facebook

Twitter

Supramolecular polymer formed by ditopic cyclodextrin and ditopic adamantane derivatives

Alvaro Antelo ¹

Mercedes Alvarez Alcalde ¹

Aida Jover ¹

Francisco Meijide ¹

Luciano Galantini ²

José Vázquez Tato ¹

1. Departamento de Química Física, Facultad de Ciencias, Universidad de Santiago de Compostela, Avda. Alfonso X El Sabio s/n, 27002 Lugo, Spain

2. Dipartimento di Chimica, Research center SOFT-INFM-CNR, Università di Roma “La Sapienza”, P.le A. Moro 5, 00185 Roma, Italy

Abstract

Novel host-guest supramolecular copolymers have been prepared from a ß-cyclodextrin (binded to ethylenediamintetraacetic acid, EDTA) dimer and a ditopic guest with two adamantyl groups bound to pyromellitic acid. Molecular weight and molecular size were determined from static and dynamic light scattering measurements (SLS and DLS, respectively). The analysis of results suggests that the supramolecular polymer adopts a shruck structure with an average molecular weight value of Mn =(1.51±0.02)×104 g·mol-1 (degree of polymerization equal to 5).

Keywords

n/a

Preliminary Evaluation of Molsidomine Imprinted Polymers

Synthesis and Characterization of a New Gemini Surfactant Derived from 3a,7a,12a-trihydroxy-5ß-cholan-24-amine (Steroid Residue) and Ethylenediamintetraacetic Acid (Spacer)