EventsThe 11th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-11-01330
This submission belongs to the session a. General Organic Synthesis of the event The 11th International Electronic Conference on Synthetic Organic Chemistry
Published date
30 Nov, 2007
Citation
Wolfgang Stadlbauer, Naresh S. Badgujar, Reactions of Acetoacetates With Electron-deficient Anilines, in Proceedings of The 11th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2007, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-11-01330
Share
Email
Facebook
Twitter
LinkedIn

Reactions of Acetoacetates With Electron-deficient Anilines

Wolfgang Stadlbauer 1
Naresh S. Badgujar 1
1. Institut für Chemie, Organic Synthesis Group, Karl-Franzens-University of Graz, Heinrichstrasse 28, A-8010 Graz, Austria
Abstract
The reaction of anilines, having electron-withdrawing substituents such as chloro- or trifluoromethyl groups, with acetoacetates was studied. Using the "watering protocol" [5], mainly acetanilides were obtained which were intended ty cyclize to 2-quinolones. However, in contrast to electron-rich anilides, it was not possible to obtain cyclized products from electron-deficient anilides.
Keywords
n/a
-7α-Alkoxyestra-1,3,5(10)-trienes
Regioselective and Sequential Mono- and Diamination of 5,7-Dichloro-pyrido[2,3-d]pyrimidine-2,4-diones