EventsThe 11th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-11-01346
This submission belongs to the session e. Symposium on Microwave Assisted Synthesis of the event The 11th International Electronic Conference on Synthetic Organic Chemistry
Published date
30 Nov, 2007
Citation
Dariusz Bogdal, Szczepan Bednarz, Microwave assisted transformation of compounds capable of internal reorientation, in Proceedings of The 11th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2007, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-11-01346
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Microwave assisted transformation of compounds capable of internal reorientation

Szczepan Bednarz 1
image
Dariusz Bogdal 2
1. Department of Engineering and Machinery for Food Industry, University of Agricultural, ul. Balicka 122, 30-149 Krakow, Poland
2. Faculty of Chemical Engineering and Technology, Politechnika Krakowska, ul. Warszawska 24, 31-155 Krakow, Poland
Abstract
The nature of microwave effects during organic syntheses is still a matter of discussion. The present study covers the unknown issue that is an influence of microwave irradiation on reactions, in which one of substrates is able to intramolecular reorientation under microwave conditions. The reactions of triphenylmethanol (i.e., dehydratation and etherification), as an example of compound with active hydroxyl group, were investigated.
Keywords
Microwave irradiation
intremolecular reorientation
relaxation time
triphenylmethanol
Thermodynamically controlled Reactions of Selenenylphosphonium Ion Me3PSeMe+ toward Electrophiles and Nucleophiles
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