Events The 26th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session S1. General Organic Synthesis of the event The 26th International Electronic Conference on Synthetic Organic Chemistry

Published date

14 Nov, 2022

Academic Editor

Julio A. Seijas

Citation

Liliya I. Tulyabaeva, Rustam R. Salakhutdinov, Tatiyana V. Tyumkina, Arthur R. Tulyabaev, Ti-catalyzed reaction of β-pinene with BF₃·THF, in Proceedings of The 26th International Electronic Conference on Synthetic Organic Chemistry, 15 November–30 November 2022, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-26-13529

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Ti-catalyzed reaction of β-pinene with BF₃·THF

Liliya I. Tulyabaeva ¹

Rustam R. Salakhutdinov ¹

Tatiyana V. Tyumkina ¹

Arthur R. Tulyabaev ¹

1. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences

Abstract

The reaction of β-pinene with BF₃·THF in the presence of the catalytic system Cp₂TiCl₂/Mg was carried out for the first time to obtain a previously undescribed 1-fluoro-substituted boraspirane. The reaction proceeds stereoselectively, but is complicated by the rearrangement of the β-pinene under the Ti-catalyzed reaction conditions.

Keywords

cycloboration

organoborane compounds

β-pinene

Cp2TiCl2.

Manuscript

sciforum_064316_Tulyabaeva_LI-done.pdf

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