EventsThe 26th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-26-13537
This submission belongs to the session S1. General Organic Synthesis of the event The 26th International Electronic Conference on Synthetic Organic Chemistry
Published date
14 Nov, 2022
Academic Editor
author-avatarJulio A. Seijas
Citation
Artur A Khuzin, Airat R. Tuktarov, Usein M. Dzhemilev, Sulfur-containing homo- and methanofullerenes, synthesis and study of tribological properties, in Proceedings of The 26th International Electronic Conference on Synthetic Organic Chemistry, 15 November–30 November 2022, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-26-13537
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Sulfur-containing homo- and methanofullerenes, synthesis and study of tribological properties

Artur A Khuzin 1
Airat R. Tuktarov 1
Usein M. Dzhemilev 1
1. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center of the Russian Academy of Sciences
Abstract

The data obtained by the authors in the field of carbon cluster chemistry, namely, the catalytic cycloaddition of sulfur-containing diazo compounds to C60-fullerene under the action of complex Pd-catalysts, are summarized. Cycloaddition reactions of diazoalkanes, diazoketones, diazothioates with C60- fullerene, catalyzed by Pd(acac)2-PPh3-Et3Al, with selective formation of new sulfur-containing methano- and homo-, and pyrazolinofullerenes, promising as modern nanosized additives to oils for highly loaded mechanisms.

Keywords
fullerenes
diazo compounds
methanofullerenes
homofullerenes
metal complex catalysis
tribology
additives
Manuscript
sciforum_065626_original_ECSOC26_MDPI_KHUZIN_A_done.pdf
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