Events The 10th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 10th International Electronic Conference on Synthetic Organic Chemistry

Published date

30 Nov, 2006

Citation

M. Soledad Pino-González, Noé Oñas Bernal, Raquel Casasola, Inmaculada Robina, Syntheses of new azepane derivatives from monosaccharides, in Proceedings of The 10th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2006, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-10-01407

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Syntheses of new azepane derivatives from monosaccharides

M. Soledad Pino-González ¹

Noé Oñas Bernal ¹

Raquel Casasola ¹

Inmaculada Robina ²

1. Departamento de Bioquímica, Biología Molecular y Química Orgánica, Facultad de Ciencias, Universidad de Málaga, 29071 Málaga, Spain

2. Departamento de Química Orgánica, Facultad de Química, Universidad de Sevilla, 41012 Sevilla, Spain

Abstract

Synthetic routes to polyhydroxy azepanes from monosaccharides are described. The stereoselective formation of trans epoxyamides and regioselective epoxyde opening led to azido derivatives that could be transformed in azepanic structures. An anomalous result was obtained in the hydrogenation in MeOH with Pd/C of the azido derivative obtained from D-mannose

Keywords

n/a

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