This submission belongs to the session d. Symposium on Selenium and Tellurium Chemistry of the event The 10th International Electronic Conference on Synthetic Organic Chemistry
Published date
30 Nov, 2006
Citation
Rogério A. Gariani, Fábio Simonelli, Alfredo R. M. Oliveira, Andersson Barison, João V. Comasseto, A Chiral Tellurium Ferrocene as a Chiral Agent in NMR Enantiomeric Purity Determination, in Proceedings of The 10th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2006, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-10-01434
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A Chiral Tellurium Ferrocene as a Chiral Agent in NMR Enantiomeric Purity Determination
Rogério A. Gariani 1
Fábio Simonelli 1
Alfredo R. M. Oliveira 1
Andersson Barison 1
João V. Comasseto 2
1. Departamento de Química, Universidade Federal do Paraná, Curitiba, CEP 81531-990, Brazil
2. Instituto de Química, Universidade de São Paulo, São Paulo, CEP 05508-900, Brazil
Abstract
The tellurium nuclear magnetic resonance spectrum of a chiral tellurium ferrocene (2) produces a single signal at different chemical shifts when solubilized together with different enantiomeric proportions of a chiral compounds.
Keywords
Tellurium ferrocene
Chiral Agent Probing
enantiomeric Purity
nuclear magnetic resonance
Tellurium / Lithium Exchange Reaction in the Synthesis of Spiroketals and 1,6-dioxigenated Systems
Microwave Assisted Oxidation of Organic Substrates Using Tetramethylammonium fluorochromate (TMAFC)