This submission belongs to the session a. General Organic Synthesis of the event The 9th International Electronic Conference on Synthetic Organic Chemistry
Published date
01 Nov, 2005
Citation
Claudia Della Rosa, Maria Kneeteman, Pedro M. E. Mancini, Behaviour of 2-nitroheterocycles in Cycloaddition Reactions, in Proceedings of The 9th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2005, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-9-01477
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Behaviour of 2-nitroheterocycles in Cycloaddition Reactions
Claudia Della Rosa 1
Maria Kneeteman 1
Pedro M. E. Mancini 1
1. Área Química Orgánica, Departamento de Química, Facultad de Ingeniería Química, Universidad Nacional del Litoral, Santiago del Estero 2829- 3000 Santa Fe, Argentina
Abstract
Five membered aromatic 2-nitroheterocycles are studied in Diels-Alder reactions. 2-nitrofuran and 1-tosil-2-nitropyrrole yielded normal cycloadducts with isoprene and Rawal´s diene. Formation of pyrrolyl-derivatives are observed in reactions of 2-nitrothiophene and 2-nitroselenophene with isoprene.
Keywords
2-nitroheterocycles
dienophiles
Diels-Alder2-nitroheterocycles
dienophiles
Diels-Alder
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