EventsThe 2nd International Electronic Conference on Chemical Sensors and Analytical Chemistry
Published
This submission belongs to the session S3. Materials for Chemical Sensing of the event The 2nd International Electronic Conference on Chemical Sensors and Analytical Chemistry
Published date
18 Sep, 2023
Academic Editor
author-avatarMarco Frasconi
Citation
Meng Zhou, Nan Gao, Ze Xu Xue, Xiao Wen Xie, Shuai Chen, Flexible PTCDIs@PEDOT films with interpenetrating P-N heterojunction and their gas sensing use, in Proceedings of The 2nd International Electronic Conference on Chemical Sensors and Analytical Chemistry, 16 September–30 September 2023, MDPI: Basel, Switzerland, doi: 10.3390/CSAC2023-14877
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Flexible PTCDIs@PEDOT films with interpenetrating P-N heterojunction and their gas sensing use

Nan Gao 2
Ze Xu Xue 2
Xiao Wen Xie 2
image
1. Flexible Electronics Innovation Institute and School of Pharmacy, Jiangxi Science & Technology Normal University, Nanchang, Jiangxi 330013, China;, China
2. Flexible Electronics Innovation Institute and School of Pharmacy, Jiangxi Science & Technology Normal University, Nanchang, Jiangxi 330013, China;
3. 1. Flexible Electronics Innovation Institute and School of Pharmacy, Jiangxi Science & Technology Normal University, Nanchang, Jiangxi 330013, China; 2.Jiangxi Provincial Engineering Research Center for Waterborne Coatings, Nanchang 330013, China
Abstract

Through the selection of N-type organic semiconductor molecules and the method of supramolecular self-assembly at the solvent phase interface, the perylene tetracarboxylic diimide (PTCDIs) nanofiber film with loose and porous morphology was constructed by in-situ deposition on the surface of ITO conductive glass. Then the P-type organic semiconducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) was grown in the fiber interweaving network of this film via quantitative electrochemical polymerization, thus preparing PTCDIs@PEDOT composite film with N-P heterojunction architecture. PTCDIs@PEDOT film has good moisture resistance and improved sensitivity and signal response for gas phase H2O2 detection.

Keywords
P-N heterojunction
PEDOT
PTCDI
vapor detection
chemosensor
Manuscript
Ambient chemiresistive sensing of hydrogen peroxide based on PEDOT:PSS/PEDOT film
Photometric determination of iron(III) with 2-napthylcarboxymethylene citrate