EventsThe 27th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-27-16045 (registering DOI)
This submission belongs to the session S1. General Organic Synthesis of the event The 27th International Electronic Conference on Synthetic Organic Chemistry
Published date
15 Nov, 2023
Academic Editor
author-avatarJulio A. Seijas
Citation
Alevtina Makhamatkhanova, Tatyana Viktorovna Tyumkina, SYNTHESIS OF 3-SUBSTITUTED 1H-PHOSPHOLANOXIDES BY THE INTERACTION OF ALUMOLANES WITH PBr₃/H₂O, in Proceedings of The 27th International Electronic Conference on Synthetic Organic Chemistry, 15 November–30 November 2023, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-27-16045
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SYNTHESIS OF 3-SUBSTITUTED 1H-PHOSPHOLANOXIDES BY THE INTERACTION OF ALUMOLANES WITH PBr3/H2O

Alevtina Makhamatkhanova 1
Tatyana Viktorovna Tyumkina 2
1. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center of the Russian Academy of Sciences, Russia
2. Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, Russia
Abstract

We have recently developed a method for the synthesis of 3R-substituted and norbornane-annelated 1H-phospholanoxides based on the reaction of replacement of aluminum atoms in alumolane with phosphorus atoms by phosphorus trichloride. . In development of our research, we have established that the use of PBr3 as a phosphorus reagent also successfully allows us to obtain target 1H-phospholanoxides.

Keywords
phospholanes
alumolane
cycloalumination
phosphorus trichloride.
Manuscript
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