Events The 27th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session S1. General Organic Synthesis of the event The 27th International Electronic Conference on Synthetic Organic Chemistry

Published date

15 Nov, 2023

Academic Editor

Julio A. Seijas

Citation

Arslan Akhmetov, Zarema R Sadretdinova, Arthur Tulyabaev, Leonard Khalilov, Hexa-substituted hybrid C60 derivatives with norbornadiene fragments: synthesis and structure, in Proceedings of The 27th International Electronic Conference on Synthetic Organic Chemistry, 15 November–30 November 2023, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-27-16104

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Hexa-substituted hybrid C60 derivatives with norbornadiene fragments: synthesis and structure

Arslan Akhmetov ¹

Zarema R Sadretdinova ¹

Arthur Tulyabaev ¹

Leonard Khalilov ¹

1. 450075 Institute of petrochemistry and catalysis of RAS Pr. Oktyabrya 141, Ufa, Russia, Russia

Abstract

New hybrid fullerene C60 derivatives with five norbornadiene fragments bound to a fullerene core by several methylene groups were synthesized for the first time. Subsequent photoirradiation of these C60 fullerene derivatives leads to only partial (up to 20%) opening of double bonds in norbornadiene fragments to form quadricyclane substituents. It is assumed that the resulting C60 fullerene derivatives can be the basis to create high-energy materials.

Keywords

C60 fullerene

high-energy materials

quadricyclane

norbornadiene

Manuscript

sciforum-081902-clean.pdf

A new synthesis of poly heterocyclic compounds containing nitrogen and boron atoms

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