EventsThe 27th International Electronic Conference on Synthetic Organic Chemistry
Published
with-doi10.3390/ecsoc-27-16110 (registering DOI)
This submission belongs to the session S4. Polymer and Supramolecular Chemistry of the event The 27th International Electronic Conference on Synthetic Organic Chemistry
Published date
15 Nov, 2023
Academic Editor
author-avatarJulio A. Seijas
Citation
Isabel García-Santos, Alfonso Castiñeiras, Manuel Saa, Structural study of {[(H4fpytsc)₂]²⁺[PF₆]–[(NO₃]–} from 4-Formylpyridine thiosemicarbazone (4fpytsc)., in Proceedings of The 27th International Electronic Conference on Synthetic Organic Chemistry, 15 November–30 November 2023, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-27-16110
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Structural study of {[(H4fpytsc)2]2+[PF6][(NO3]} from 4-Formylpyridine thiosemicarbazone (4fpytsc).

Manuel Saa 1
1. Department of Inorganic Chemistry, Faculty of Pharmacy, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain, Spain
Abstract

In the present research, bis(Pyridinium-4-carbaldehyde thiosemicarbazone) hexafluorophosphate, nitrate (1) have been prepared by protonation of 4-Formylpyridine thiosemicarbazone (4fpytsc, 2). The compound 1 and the starting thiosemicarbazone have been well characterized and their molecular and crystal structures were studied by single-crystal X-ray diffraction. The supramolecular assembly of each crystal is also analyzed and discussed.

Keywords
Thiosemicarbazones
pyridinium salts
supramolecular architectures
hydrogen bond
Manuscript
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