EventsThe 27th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-27-16143
This submission belongs to the session S1. General Organic Synthesis of the event The 27th International Electronic Conference on Synthetic Organic Chemistry
Published date
15 Nov, 2023
Academic Editor
author-avatarJulio A. Seijas
Citation
Cristina González-Barreira, Julio Corredoira-Vázquez, Ana M. García-Deibe, Matilde Fondo, Synthesis of a dysprosium(III) complex with a hexadentate amine ligand , in Proceedings of The 27th International Electronic Conference on Synthetic Organic Chemistry, 15 November–30 November 2023, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-27-16143
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Synthesis of a dysprosium(III) complex with a hexadentate amine ligand

Cristina González-Barreira 1
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Julio Corredoira-Vázquez 1,2
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Ana M. García-Deibe 1
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Matilde Fondo 1
1. Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain, Spain
2. Phantom-g, CICECO – Aveiro Institute of Materials, Department of Physics, University of Aveiro, 3810-193 – Aveiro, Portugal
Abstract

The use of polydentate macrocyclic Lewis bases is a way to contribute to determine the coordination number of metal complexes. In this way, hexadentate N6 donors can help to achieve lanthanoid complexes with coordination number 8. But the geometry of these complexes depends on the flexibility of the bases. In this way, in this communication we present the synthesis and crystallographic characterization of the dysprosium complex [DyLN6Cl2]Cl·2H2O, where LN6 is a flexible hexaaza donor.

Keywords
Hexaaza donor
dysprosium
flexible macrocycle
Manuscript
sciforum-081169-clean.pdf
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