Events The 27th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session S1. General Organic Synthesis of the event The 27th International Electronic Conference on Synthetic Organic Chemistry

Published date

15 Nov, 2023

Academic Editor

Julio A. Seijas

Citation

Paula Oreiro-Martínez, Julio Corredoira-Vázquez, Jesús Sanmartín-Matalobos, Matilde Fondo, An optimised method to synthesise N₅O₂ aminophenols , in Proceedings of The 27th International Electronic Conference on Synthetic Organic Chemistry, 15 November–30 November 2023, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-27-16145

Facebook

Twitter

An optimised method to synthesise N₅O₂ aminophenols

Paula Oreiro-Martínez ¹

Julio Corredoira-Vázquez ^2,3

Jesús Sanmartín-Matalobos ^4,5

Matilde Fondo ²

1. Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain

2. Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain., Spain

3. Phantom-g, CICECO – Aveiro Institute of Materials, Department of Physics, University of Aveiro, 3810-193 – Aveiro, Portugal.

4. Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain., Spain

5. Institute of Materials (iMATUS), Universidade de Santiago de Compostela, 15782 Santiago de Compostela, Spain.

Abstract

Aminophenol compounds are usually employed in coordination chemistry due to their versatility to form metal complexes. Heptadentate N₅O₂ aminophenol ligands can lead to the obtention of lanthanoid complexes with pentagonal bypiramidal (pbp) geometry, which are very interesting in the field of molecular magnetism. In this communication we report an optimised method for obtaining two similar N₅O₂ aminophenols named 2-((((6-(((5-hydroxy-2-R-benzyl)(pyridin-2-ylmethyl)amino)methyl)pyridin-2-yl)methyl)(pyridin-2-ylmethyl)amino)methyl)-4-R-phenol (R = methyl or methoxy), which significantly improves the few examples of synthesis of this type of compound reported in literature.

Keywords

aminophenol

N,O donor

heptadentate ligand

Manuscript

sciforum-081073-clean.pdf

Anti-microbial activity, Antioxidant and Antidiarrheal activities of the Leaf extracts of Carica papaya L. and Psidium guajava L.

Synthesis of C60 fullerene hexakis adducts based on strained polycyclic hydrocarbons and their application in organic electronics

An optimised method to synthesise N5O2 aminophenols

An optimised method to synthesise N₅O₂ aminophenols