This submission belongs to the session a. General Organic Synthesis of the event The 13th International Electronic Conference on Synthetic Organic Chemistry
Published date
31 Oct, 2009
Citation
Pierre Grandclaudon, Éric Deniau, Axel Couture, Stéphane Lebrun, Photochemically-Induced N-N Bond Cleavage of N,N-Disubstituted Hydrazides, in Proceedings of The 13th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2009, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-13-00167
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Photochemically-Induced N-N Bond Cleavage of N,N-Disubstituted Hydrazides
Pierre Grandclaudon 1
Éric Deniau 1
Axel Couture 1
Stéphane Lebrun 1
1. UMR CNRS 8009 "Chimie Organique et Macromoléculaire", Université des Sciences et Technologies de Lille 1, Laboratoire de Chimie Organique Physique, Bâtiment C3(2), F-59655 Villeneuve d'Ascq Cedex, France
Abstract
The development of an unprecedented methodology based upon direct photolysis of N,N-disubstituted hydrazides to secure N-N bond cleavage and to trigger off the formation of NH free lactams has been disclosed.
Keywords
Asymmetric Synthesis of 1- ,3- or 4-Alkyl- or Aryl- Tetrahydro-Benzo[c]azepines
Synthesis and Mesogenic Properties of New Schiff Bases Comprising Benzothiazole Moiety