Events The 2nd International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 2nd International Electronic Conference on Synthetic Organic Chemistry

Published date

01 Nov, 1998

Citation

Julio A. Seijas, M. Pilar Vàsquez-Tato, Luis Barreiro-Castro, Reactivity of styrene derivatives: Nucleophilic addition versus 1,2-wittig rearrangement, in Proceedings of The 2nd International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 1998, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-2-01670

Facebook

Twitter

Reactivity of styrene derivatives: Nucleophilic addition versus 1,2-wittig rearrangement

Julio A. Seijas ¹

M. Pilar Vàsquez-Tato ¹

Luis Barreiro-Castro ¹

1. Departamento de Química Orgánica. Universidad de Santiago de Compostela. Facultad de Ciencias. Aptdo. 280, 27080 Lugo, Spain

Abstract

Wittig rearrangements have been studied for a long time, the [2,3]-rearrangement being the most widely studied, and there are many reports on its mechanistic and synthetic applications {1}. The corresponding [1,2]-rearrangement has been studied too, but has not been so widely used as a synthetic tool, remaining mainly as a competitive reaction that interferes with the other possible rearrangements.

Keywords

n/a

Thermal Cyclization of 2-Hydrazonoacyl-3-oxo-heterocycles to Pyrazolo[4,3-c]fused Heterocycles

Synthesis of 2-Alkylbenzoic Acids: Alkyllithium Additions to 2-Vinylbenzoic Acid