Events The 2nd International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 2nd International Electronic Conference on Synthetic Organic Chemistry

Published date

01 Nov, 1998

Citation

F. Javier Sardina, Didier Villemin, Belkacem Nechab, Use of a new hydrophilic phosphonic phosphines (DPPA). Heck Reaction in Aqueous Medium under Microwave Irradiation., in Proceedings of The 2nd International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 1998, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-2-01674

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Use of a new hydrophilic phosphonic phosphines (DPPA). Heck Reaction in Aqueous Medium under Microwave Irradiation.

Didier Villemin ¹

Belkacem Nechab ¹

F. Javier Sardina ¹

1. Ecole Nationale Superieure d' Ingenieurs de Caen, I.S.M.R.A., Universite de Caen UMR CNRS 6507, 6 Boulevard du Marechal Juin F-14050 Caen Cedex, France

Abstract

The Heck reaction is efficiently and rapidly obtained by a palladium-catalysed reaction in water performed in a Teflon autoclave under microwave irradiation with a commercial microwave oven. Water soluble phosphine-ligand catalysts and phase transfer catalysis conditions are used.

Keywords

Heck reaction

Microwaves

Phase-transfer catalysis

Water-soluble phosphine

LogP

DPPA

Enantiospecific, Stereoselective Synthesis of Enantiomerically Pure Aziridine-2-carboxylic Acids from Aspartic Acid

Synthesis and investigation of 2- hydroxyaryl(5-methylfur-2-yl) alkanes.