EventsThe 3rd International Electronic Conference on Synthetic Organic Chemistry
Published
This submission belongs to the session a. General Organic Synthesis of the event The 3rd International Electronic Conference on Synthetic Organic Chemistry
Published date
01 Nov, 1999
Citation
Ronald N. Warrener, Martin R. Johnston, Davor Margetic, Functionalised Rigid Rods - Dream or Reality, in Proceedings of The 3rd International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 1999, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-3-01727
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Functionalised Rigid Rods - Dream or Reality

Davor Margetic 1
Martin R. Johnston 1
Ronald N. Warrener 1
1. Director, Centre for Molecular Architecture, Central Queensland University, Bruce Highway, ROCKHAMPTON QLD 4702
Abstract
Approaches to the synthesise of rigid molecular rods containing syn-facially positioned 7-oxa functionality the building BLOCK 12 was identified by molecular modelling as a suitable starting substrate. However, once synthesised, 12 was found to be unstable under the reaction conditions used in an attempt to create rigid rods. This included such coupling protocols as the epoxide based ACE reaction as well as the s-tetrazine system. The foundations have now been laid for future incorporation of 12 into rigid rods.
Keywords
n/a
New routes to dibenzobarrelene and pyrimidinobenzobarrelenes: a synthetic and computational study
Site and Stereoselectivities in the High Pressure Reactionof Furan with Dimethyl 7-isopropylidenebicyclo[2.2.1]hepta-2,5-diene-2,3-dicarboxylate and Tetramethyl7-isopropylidenebicyclo[2.2.1]hepta-2,5-diene-2,3,5,6-tetracarboxylate.