Events The 13th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 13th International Electronic Conference on Synthetic Organic Chemistry

Published date

31 Oct, 2009

Citation

Thies Thiemann, Kyoko Yamamoto, Suzuki-Miyaura cross-coupling and Heck reactions catalysed by Pd on carbon nanofibres, in Proceedings of The 13th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2009, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-13-00173

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Suzuki-Miyaura cross-coupling and Heck reactions catalysed by Pd on carbon nanofibres

Thies Thiemann ^1,2

Kyoko Yamamoto ¹

1. Interdisciplinary Graduate School of Engineering Sciences, Kyushu University, 6-1, Kasugakoh- en, Kasuga-shi 816-8580, Fukuoka-ken, Japan

2. Present address: Department of Chemistry, Faculty of Sciences, United Arab Emirates University, PO Box 17551, Al Ain, United Arab Emirates

Abstract

Platelet, tubular and herring-bone carbon nanofibres were doped with Pd under various conditions. The catalysts were analysed as to the Pd-content and as to the size distribution of the Pd particles. The Pd-doped carbon nanofibres were screened for their catalytic activity in the Suzuki-Miyaura cross coupling and in the Heck reaction.

Keywords

Carbon nanofibres

Heck reaction

Suzuki-Miyaura cross coupling

ultrasonication

catalysis

Oxidative degradation of a steroidal isoxazoline: 1-formyl-7-methoxy-2-methylphenanthrene from 3\'-methoxyestra-1\',3\',5\'(10\')-trieno(16\',17\':4,5)isoxazoline

Diastereoselective direct aldol reaction and subsequent cyclization of 2-azetidinone-tethered azides for the preparation of a 4-hydroxypipecolic acid analogue