EventsThe 4th International Electronic Conference on Synthetic Organic Chemistry
Event submissions
Published
with-doi10.3390/ecsoc-4-01796
This submission belongs to the session a. General Organic Synthesis of the event The 4th International Electronic Conference on Synthetic Organic Chemistry
Published date
11 Sep, 2000
Citation
Katsuhiko Inomata, Yutaka Ukaji, Asymmetric 1,3-Dipolar Cycloaddition Utilizing Tartaric Acid Ester as a Chiral Auxiliary, in Proceedings of The 4th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2000, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-4-01796
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Asymmetric 1,3-Dipolar Cycloaddition Utilizing Tartaric Acid Ester as a Chiral Auxiliary

Yutaka Ukaji 1
Katsuhiko Inomata 1
1. Department of Chemical Science, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma, Kanazawa, Ishikawa 920-1192, Japan
Abstract
In order to develop a practical method for the construction of chiral molecules, we have designed a novel chiral system possessing two metal centers utilizing tartaric acid esters. Based on this concept, catalytic asymmetric 1,3-dipolar cycloaddition of nitrile oxides and nitrones could be achieved with an high level of stereocontrol.
Keywords
n/a
Enantioselective Intramolecular CH-Insertions upon Cu- Catalyzed Decomposition of Phenyliodonium Ylides
Synthetic Applications of the Asymmetric Amino-Cope Rearrangement