Events The 13th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 13th International Electronic Conference on Synthetic Organic Chemistry

Published date

31 Oct, 2009

Citation

Saad S. Elmorsy, Tarek A. Salama, Silicon Assisted Halogenation I: A Convenient Synthesis of β-chloroketones via Reaction of α,β-unsaturated ketones with Tetrachlorosilane-Phenol, in Proceedings of The 13th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2009, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-13-00181

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Silicon Assisted Halogenation I: A Convenient Synthesis of β-chloroketones via Reaction of α,β-unsaturated ketones with Tetrachlorosilane-Phenol

Saad S. Elmorsy ¹

Tarek A. Salama ^1,2

1. Chemistry Department, Faculty of Science, Mansoura University, 35516-Mansoura, Egypt

2. Chemistry Department, Faculty of Education, Amran University, Amran, Yemen

Abstract

A combination of tetrachlorosilane (TCS) and phenol in dichloromethane was found to be an efficient reagent for hydrochlorination of α,β- unsaturated ketones to afford the corresponding β-chloroketones in good yield at ambient temperature.

Keywords

Synthesis of N-substituted-3,4,5,6-tetrachlorophthalimide using trichloroacetimidate C-C bond formation method

SYNTHESIS OF HIGHLY FUNCTIONALIZED NON-RACEMIC CHIRAL ALKYL HALIDES USING KHARASCH ADDITION