This submission belongs to the session a. General Organic Synthesis of the event The 4th International Electronic Conference on Synthetic Organic Chemistry
Published date
11 Sep, 2000
Citation
Manuel Gonzalez-Sierra, Raquel M. Cravero, Guillermo R. Labadie, Epoxidation Studies of Decalin-1,4-dienones and related Alcohols, in Proceedings of The 4th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2000, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-4-01813
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Epoxidation Studies of Decalin-1,4-dienones and related Alcohols
Guillermo R. Labadie 1
Raquel M. Cravero 1
Manuel Gonzalez-Sierra 1
1. IQUIOS-(Instituto de Química Orgánica de Síntesis), Departamento de Química Orgánica, Facultad de Ciencias Bioquímicas y Farmacéuticas, UNIVERSIDAD NACIONAL DE ROSARIO. Suipacha 531- SL2002LRK-Rosario-Santa Fe- ARGENTINA
Abstract
The regio- and diastereoselectivities of epoxidations of decalin-1,4 -dienones and dienols obtained from the Birch reduction alkylation of different a-tetralones is described. They appear to depend on the steric approach control of the peracid and show an important contribution of the directing effect of homoallylic alcohols
Keywords
n/a
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