Events The 4th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 4th International Electronic Conference on Synthetic Organic Chemistry

Published date

11 Sep, 2000

Citation

Martin R. Johnston, Melissa J. Latter, Ronald N. Warrener, Mirta Golic, Dan McKavanagh, Davor Margetic, Diels-Alder cycloadditions of 1,3-cyclohexadien-4,5-diones(o-benzoquinones) with norbornadiene. Part I. Synthesis., in Proceedings of The 4th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2000, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-4-01837

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Diels-Alder cycloadditions of 1,3-cyclohexadien-4,5-diones(o-benzoquinones) with norbornadiene. Part I. Synthesis.

Martin R. Johnston ¹

Melissa J. Latter ¹

Ronald N. Warrener ¹

Mirta Golic ¹

Dan McKavanagh ¹

Davor Margetic ¹

1. Centre for Molecular Architecture, Central Queensland University, North Rockhampton, 4701, QLD, Australia

Abstract

Cycloadditions between o-chloranil and norbornadiene produced a range of geometrical variants which were characterised as quinoxaline derivatives. Two ether products were also observed resulting from hetero Diels-Alder reactions. Photochemical irradiation of 20 produced the cage compound 22 as a result of an internal (2+2)p cycloaddition.

Keywords

n/a

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