Events The 4th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 4th International Electronic Conference on Synthetic Organic Chemistry

Published date

11 Sep, 2000

Citation

Sebastien Reymond, Martin Smith, Jean Michel Brunel, Enantioselective Palladium Catalyzed Allylic Substitution with New Multichiral Centers Monophosphine Ligands, in Proceedings of The 4th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2000, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-4-01841

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Enantioselective Palladium Catalyzed Allylic Substitution with New Multichiral Centers Monophosphine Ligands

Jean Michel Brunel

Martin Smith

Sebastien Reymond

Abstract

The synthesis of new multichiral center monophosphine ligands 1-3 was achieved and assessed in the enantioselective palladium catalyzed allylic substitution of 1,3-diphenyl-2-propenyl acetate 4 with enantioselectivities up to 92%

Keywords

n/a

First Pd(0)-Catalyzed (Allylic Alkylation / Heck) Domino Sequence

A Highly Stereoselective Synthesis of Carbamate Protected anti-1,2-Aminoalcohols