Events The 13th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session a. General Organic Synthesis of the event The 13th International Electronic Conference on Synthetic Organic Chemistry

Published date

31 Oct, 2009

Citation

Carmen Sañudo, Alfonso González, Patricia Val, Sergio Ferrero, Alberto Diez de la Varga, Raquel Abad, Asunción Barbero, Francisco J. Pulido, METHYLENE INSERTION IN VINYLCUPRATES BEARING AN ALLYLIC SILYL GROUP, in Proceedings of The 13th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2009, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-13-00185

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METHYLENE INSERTION IN VINYLCUPRATES BEARING AN ALLYLIC SILYL GROUP

Carmen Sañudo ¹

Alfonso González ¹

Patricia Val ¹

Sergio Ferrero ¹

Alberto Diez de la Varga ¹

Raquel Abad ¹

Asunción Barbero ¹

Francisco J. Pulido ¹

1. Departamento de Química Orgánica, Universidad de Valladolid, 47011 Valladolid, Spain

Abstract

The silylcupration of allene has emerged as a useful tool for the synthesis of functionalized allylsilanes which have been used in the synthesis of different-sized carbocycles. We now described the preparation of allylsilane-allylcuprate intermediates by homologation reaction with iodomethylzinc iodide and their reaction with different electrophiles.

Keywords

N-Alkyl-N-[5-(propylamino)-9H-benzo[a]phenoxazin-9-ylidene]alkan-1- aminium chlorides: synthesis and photophysical studies

Solvent-free synthesis of Thiocarbamic acid [(furan-2-yl) ethylidene] hydrazide under ball-milling conditions