Events The 4th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

This submission belongs to the session b. Solid Phase Chemistry and Combinatorial Synthesis of the event The 4th International Electronic Conference on Synthetic Organic Chemistry

Published date

11 Sep, 2000

Citation

Andreas Kirschning, Andreas Schonberger, Nuria Merayo, Georgia Sourkouni-Argirusi, Silvie Dohmann, Cohalogenation of Allyl- and Vinylsilanes using Polymer-bound Haloate(I)-Reagents, in Proceedings of The 4th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2000, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-4-01881

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Cohalogenation of Allyl- and Vinylsilanes using Polymer-bound Haloate(I)-Reagents

Silvie Dohmann ¹

Georgia Sourkouni-Argirusi ¹

Nuria Merayo ¹

Andreas Schonberger ¹

Andreas Kirschning ¹

1. Institut fur Organische Chemie der Technischen Universitat Clausthal, Leibnizstrasse 6, D-38678 Clausthal-Zellerfeld, Germany

Abstract

Polymer-supported electrophilic halogenate(I) complexes 2 and 3 promote smooth addition to vinyl and allylsilanes without loss of the silyl group. In conjunction with Amberlyst A26 (OHs -form) vinyl silanes are converted into epoxysilanes in one pot.

Keywords

n/a

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