EventsThe 8th International Electronic Conference on Synthetic Organic Chemistry
Published
This submission belongs to the session a. General Organic Synthesis of the event The 8th International Electronic Conference on Synthetic Organic Chemistry
Published date
01 Nov, 2004
Citation
Vladimir N. Bulavka, Reduction of Alkylarylketones to Alkylbenzenes with Zinc D and Hydrochloric Acid: Comparison with Zinc Amalgam Reduction, in Proceedings of The 8th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2004, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-8-01959
Share
Email
Facebook
Twitter
LinkedIn

Reduction of Alkylarylketones to Alkylbenzenes with Zinc D and Hydrochloric Acid: Comparison with Zinc Amalgam Reduction

Vladimir N. Bulavka 1
1. Slavich Company, Mendeleev sq. 2, Pereslavl-Zalesskiy, Yaroslavl region, 152020, Russian Federation
Abstract
The new method of arylalkylketones Clemmensen reduction to alkylbenzenes with zinc dust and hydrochloric acid was elaborated. A comparison of arylalkylketones Clemmensen reduction with zinc amalgam literature method was made. The direction of reaction is the same, the yield of alkylbenzenes is often slightly higher. The conditions of reaction are the same or slightly milder than classic conditions.
Keywords
Clemmensen reaction
Clemmensen reduction
zinc dust
zinc amalgam
alkylarylketones
alkylbenzenes
Oxidative Iodination of Various Deactivated Arenes with I2 or KI in Concentrated Sulfuric Acid, and with Sodium Periodate Added as the Oxidant
Synthesis of Asymmetrically Meso-Substituted Porphyrins Bearing Amino Groups as Potential Cationic Photodynamic Agents