Events The 8th International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

10.3390/ecsoc-8-01971

This submission belongs to the session a. General Organic Synthesis of the event The 8th International Electronic Conference on Synthetic Organic Chemistry

Published date

01 Nov, 2004

Citation

Khadija Moughamir, Christian Rolando, Florence Charbonnier, Alpha Fluorination of Ketones by F+ Transfer Using a Precursor of MnF4, in Proceedings of The 8th International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 2004, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-8-01971

Facebook

Twitter

Alpha Fluorination of Ketones by F+ Transfer Using a Precursor of MnF4

Khadija Moughamir ¹

Christian Rolando ²

Florence Charbonnier ³

1. Université Sidi Mohamed Ben Abdellah, Faculté des Sciences et Techniques, Laboratoire de Chimie Organique, Fès-Saïs 30000 Fès, Maroc

2. Université des Sciences et Technologies de Lille (Lille 1), Chimie Organique et Macromoléculaire, 59655 Villeneuve d’Ascq, France

3. Université Joseph Fourier (Grenoble 1), UREC-IMAG (150 rue de la Chimie) - BP53, 38041 Grenoble Cedex 9, France

Abstract

Alpha fluorination of ketones is carried out under very mild conditions by using manganese (IV) dioxide and pyridinium polyhydrogenofluoride. Working up is simple and yields are good. Results are consistent with the couple MnO2 / PyHF acting as a precursor of manganese (IV) tetrafluoride formed in situ.

Keywords

manganese (IV) dioxide

manganese (IV) tetrafluoride

alpha fluoroketones

Benzylation of 2-Benzylisoindoline-1,3-diones via Photoinduced Electron Transfer. Photoinitiated Tin-Free Radical Additions to Cyclic Imides

Substituted Pyrazinecarboxamides: Preparation and Biological Activity