Events The 1st International Electronic Conference on Synthetic Organic Chemistry

Event submissions

Published

10.3390/ecsoc-1-02006

This submission belongs to the session a. General Organic Synthesis of the event The 1st International Electronic Conference on Synthetic Organic Chemistry

Published date

01 Sep, 1997

Citation

Fulgencio Tovar, Angel Vidai, Pedro Molina, Mateo Alajarín, Intramolecular Aza-Wittig Reaction of Iminophosphoranes with the b-Lactam Carbonyl Group, in Proceedings of The 1st International Electronic Conference on Synthetic Organic Chemistry, 1 November–30 November 1997, MDPI: Basel, Switzerland, doi: 10.3390/ecsoc-1-02006

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Intramolecular Aza-Wittig Reaction of Iminophosphoranes with the b-Lactam Carbonyl Group

Mateo Alajarín ¹

Pedro Molina ¹

Angel Vidai ¹

Fulgencio Tovar ¹

1. Departamento de Química Orgánica, Facultad de Química, Universidad de Murcia, Campus de Espinardo, E-30071, Murcia, Spain

Abstract

The aza-Wittig reaction1 of iminophosphoranes ([lambda]5-phosphazenes, phosphine imines) with carbonyl compounds, when carried out inter- or intramolecularly, leads to the formation of C=N double bonds, usually under neutral and mild reaction conditions. Several review articles1,2 have appeared recently reporting the increasing significance of the aza-Wittig reaction in organic synthesis, basically in the preparation of nitrogen-containing heterocyclic compounds.

Keywords

n/a

Nucleophilic Additions of 2-Furyllithium to Carbonyl Derivatives of L-Serine. Formal Synthesis of (2R,3R)-b-Hydroxy Aspartic Acid.

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